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New applications of dithiocarbamates in organic synthesis

✍ Scribed by Richard S. Grainger; Paolo Innocenti


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
196 KB
Volume
18
Category
Article
ISSN
1042-7163

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✦ Synopsis


Abstract

The application of dithiocarbamates in group transfer radical cyclization reactions is described. Carbamoyl diethyldithiocarbamates are synthesized in two high‐yielding steps from secondary amines and act as sources of carbamoyl radicals through chemical or photochemical initiation. Group transfer radical cyclization reactions lead to dithiocarbamate‐functionalized lactams. Β© 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:568–571, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20336


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## Abstract For Abstract see ChemInform Abstract in Full Text.