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New Anions of Pentacoordinate Phosphorus Containing Fluorine and Trifluoromethyl Groups

✍ Scribed by Natalya V. Pavlenko; Lesya A. Babadzhanova; Igor I. Gerus; Yurii L. Yagupolskii; Wieland Tyrra; Dieter Naumann


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
150 KB
Volume
2007
Category
Article
ISSN
1434-1948

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The Role of the 2,4,6-Tris(trifluorometh
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The reactions of potassium Rf-amide [R, = tris(trifluor0methyl)phenyl] (2) with PCl,, AsC13, and GeC1, 'dioxane yield new four-membered inorganic heterocycles [R,NPCl], (3), [RfNAsC1], (4), and [RfNGeI2 (5), respectively. On the other hand, the reaction of Rf-amide 2 with two equivalents of RfPCla l