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New anionic rearrangements. VIII. 1,4-Anionic rearrangement of silylethylenediamines

✍ Scribed by West, Robert.; Ishikawa, Mitsuo.; Murai, Shinji.

Book ID
127187139
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
625 KB
Volume
90
Category
Article
ISSN
0002-7863

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Anionic 1,4 O→C silyl rearrangements
Anionic 1,4 O→C silyl rearrangements
✍ Christoph RΓΌcker πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 215 KB

y-Silyloxy-alkyl phenyl thioethers are transformed into y-silylalcohols by treatment with lithium di-tert-butylbiphenyl. In the preceding communication 1) the 1,3 O--C migration of silyl groups in carbanions made by deprotonation of ketone silyl enol ethers was described. In the present note simila