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New anionic rearrangements. VI. Condensation of organosilylethylenediamines to silaimidazolidines

✍ Scribed by West, Robert.; Ishikawa, Mitsuo.

Book ID
127245386
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
263 KB
Volume
89
Category
Article
ISSN
0002-7863

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A/~trac~ A new type of anionic Β’yelization has been discovered in which the condensation of alkyl benzoates with simple nitriles, induced by an excess of LDA, leads directly to substituted-3-amino-2-indan-l-ones. The corresponding intermediL.t,~-[~-oxmitriles undergo cyclization to give, in most ins