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New anilinotropone-based titanium complexes: synthesis, characterization and application as catalysts for olefin polymerization

✍ Scribed by Mazzeo, Mina; Lamberti, Marina; Tuzi, Angela; Centore, Roberto; Pellecchia, Claudio

Book ID: 125529205
Publisher: Royal Society of Chemistry
Year: 2005
Tongue: English
Weight: 239 KB
Volume: 18
Category: Article
ISSN: 1477-9226
DOI: 10.1039/B506079F

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## Abstract The mixed‐ligand complexes [Ti~2~(μ‐OR)~2~(OR)~2~(κ^3^‐tbop)~2~] (1a) for R = Me and (1b) R = Et were prepared by the reaction of Ti(OR)~4~ and H~2~tbop {H~2~tbop = 2,2′‐thiobis[4‐(1,1,3,3‐tetramethylbutyl)phenol]} in methanol. Treatment of 1a and 1b with AlMe~3~ led to the substitution