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New and Efficient Syntheses of α-Iodo-α,α-Difluoro- and β-Iodo-α,α,β,β-Tetrafluorocarboxylic Acid Derivatives as Useful Building Blocks for Making Functional Fluoro Compounds †

✍ Scribed by Hung, Ming-H.; Long, Lu; Yang, Zhen-Yu


Book ID
127314739
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
72 KB
Volume
69
Category
Article
ISSN
0022-3263

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The Diels-Alder reaction of the title compound 4 and octatrienol 10, which were prepared from 44methoxy-5-methylene-2(5H)-furanone and furfuryl alcohol or D-glyceraldehyde, respectively, produced in high yield a mixture of stereo-and regio-isomeric spirotetronates: 14, X5, and 16 in about 65:25:10 r