New and Efficient Enantiospecific Synthesis of (-)-Methyl 5-epi-Shikimate and Methyl 5-epi-Quinate from (-)-Quinic Acid. -Starting from (-)-quinic acid (I) as readily available and inexpensive educt, (-)-methyl 5-epi-shikimate (VI) and methyl 5-epi-quinate (XI) are prepared. The key sequence invol
New and efficient enantiospecific synthesis of (−)-Methyl 5-epi-shikimate and methyl 5-epi-quinate from (−)-quinic acid
✍ Scribed by Susana Fernández; Mónica Díaz; Miguel Ferrero; Vicente Gotor
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 208 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Enantiospecific Synthesis of (-)-5-epi-Shikimic Acid and (-)-Shikimic Acid. -The key step in the synthesis of the title compounds (XI) and (XVI) is the intramolecular cycloaddition of the nitrones (V) and (XIV). -
## Enantioselective synthesis of (+)-shikimic acid and (+)-5.epi-shikimic acid by asymmetric Diels-Alder reaction of (S)-tx-sulfinylacrylates
## Abstract The enantioselective synthesis of [5‐^2^H]‐5‐epi‐shikimic acid starting from commercially available L‐shikimic acid has been accomplished in this work. The introduction of the stable isotope was facilitated by an enzymic reduction of a ketone. An interesting stereospecific enolisation w