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New and convenient synthesis of 1-aryl-1,2-alkanediones

✍ Scribed by De Kimpe, Norbert; Verhe, Roland; De Buyck, Laurent; Schamp, Niceas


Book ID
126972975
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
433 KB
Volume
43
Category
Article
ISSN
0022-3263

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A convenient synthesis of 2-alkyl- and 2
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%Alkyl-and 2-aryl-1,3-benxodithioles are obtained in high yield by the reaction of Grignard reagents or lithium alkyls with 2-alkoxy-1,3-benaodithioles,themaelves available in one step from anthranilic acid. In connection with our studies of the reactions of acyl carbanion equivalents with organobo