New aluminum-based ionic liquids: Synthesis, characterization, and theoretical study

✍ Scribed by Hossein Tavakol; Saeed Hatami; Shahryar Ghammamy; Gholamreza Rezaei Bebahani; Fahmideh Shabani

• Book ID: 102232963
• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 190 KB
• Volume: 20
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/hc.20564

✦ Synopsis

Abstract

Synthesis, characterization, spectral and molecular parameters of some new room‐temperature ionic liquids (tetraalkylammonium bromotrichloro aluminum [R~4~N]^+^[AlCl~3~Br]^−^) have been studied in the present study. All synthesized ionic liquids were characterized by IR, ^1^H, ^13^C, and ^81^Br‐NMR. In addition, synthesized structures were optimized at the B3LYP/LANL2DZ level of theory and then the structures, molecular specifications, and infrared spectra of these were extracted using Gaussian 03 program. Theoretical data show good agreement with the experimental results. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 20:398–404, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20564