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New allylstannanes for the connective construction of monoprotected vicinal diols

✍ Scribed by Gary E Keck; Duain E Abbott; Michael R Wiley


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
232 KB
Volume
28
Category
Article
ISSN
0040-4039

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A novel method is reported for the transformation of vicinal diols to olefins. This methodology consists in the conversion of iodothiocarbonates such as 16 to olefin 17 with phenyl lithium in excellent yield. Compounds 7 and 12 were prepared by this methodology in order to determine if they would be