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New adsorption-condensation theory for adsorption of vapors on porous activated carbons

โœ Scribed by Shivaji Sircar


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
872 KB
Volume
25
Category
Article
ISSN
0008-6223

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โœฆ Synopsis


A

new analytical model to describe equilibrium adsorption of condensable vapors on porous adsorbents is developed. It accounts for the heterogeneous pore structure of the adsorbent, adsorption in the micropores by a pore filling mechanism and adsorption and condensation in the macropores. A gamma-type pore size distribution function is used. Langmuir-type adsorption equations are used to describe both micropore filling and adsorption on the macropore walls. The vapor condensation in the pores is described by the Kelvin equation. The model is successfully tested using isotherm data for adsorption of various condensable vapors on different porous activated carbons and charcoals. All three types (I, IV and V) of adsorption isotherms by the Brunauer classification which are depicted by the porous adsorbents can be described by the model.


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