𝔖 Bobbio Scriptorium
✦   LIBER   ✦

New accessory for studies of isotopic1H/2H exchange and biomolecular interactions using transmission infrared spectroscopy

✍ Scribed by Arantxa Rodríguez-Casado; Marina Molina; Pedro Carmona

Book ID
105890008
Publisher
Springer
Year
2006
Tongue
English
Weight
241 KB
Volume
385
Category
Article
ISSN
1618-2650

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The kinetics of the isotope exchange reactions of RCH(COOH) 2 (R"H, D, Me, Et, Bu, and Ph) in D 2 O solution were studied by using 1 H NMR spectroscopy. It was observed that the rate of isotope exchange reaction was inhibited by the presence of 1 M of DNO 3 , DCl, DBr or D 2 SO 4 and catalyzed by th