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Neutron diffraction study of the oxychloride layered perovskite, (CuCl)LaNb2O7

✍ Scribed by Gabriel Caruntu; Thomas A. Kodenkandath; John B. Wiley

Book ID
114066018
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
119 KB
Volume
37
Category
Article
ISSN
0025-5408

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Construction of a double-layered tetrahe
Construction of a double-layered tetrahedral network within a perovskite host: Two-step route to the alkali-metal-halide layered perovskite, (LixCl)LaNb2O7
✍ Liliana Viciu; Thomas A. Kodenkandath; John B. Wiley πŸ“‚ Article πŸ“… 2007 πŸ› Elsevier Science 🌐 English βš– 911 KB

A two-step topotactic route is used to construct lithium halide layers within a perovskite host. Initially RbLaNb 2 O 7 is converted to (CuCl)LaNb 2 O 7 by ion exchange and then reductive intercalation with n-butyllithium is used to form (Li x Cl)LaNb 2 O 7 . The copper metal byproduct from the redu