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Neutron diffraction study of the orientational disorder in Ni(ND3)6Br2

โœ Scribed by A. Hoser; W. Prandl; P. Schiebel; G. Heger


Book ID
112513665
Publisher
Springer
Year
1990
Tongue
English
Weight
455 KB
Volume
81
Category
Article
ISSN
1434-6036

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Neutron powder di4raction on Mg(ND 3 ) 2 Cl 2 and Mg(ND 3 ) 2 Br 2 revealed as a function of temperature uniaxial orientational order+disorder behavior of the ND 3 groups. The crystal structures of both compounds are built up from chains of octahedra 1 [Mg(NH 3 ) 2 X 4/2 ] with X โ€ซุโ€ฌ Cl and Br arran

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A member of the series M(I)M(III)(ND 3 ) 6 (ClO 4 ) 2 X 2 , CsCo(ND 3 ) 6 (ClO 4 ) 2 Cl 2 , has been examined by single crystal time-of-6ight neutron di4raction at 20, T c ุŠ10, T c ุ‰10, and 290 K, adding to previous X-ray di4raction studies of some compounds in this series. T c is the phase transiti