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Neutral η6-arene ruthenium complexes with monodentate P-donor ligands

✍ Scribed by Grabulosa, Arnald; Mannu, Alberto; Alberico, Elisabetta; Denurra, Stefania; Gladiali, Serafino; Muller, Guillermo

Book ID
119328546
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
585 KB
Volume
363-364
Category
Article
ISSN
1381-1169

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✍ Ralf Stodt; Susan Gencaslan; Iris M. Müller; William S. Sheldrick 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 235 KB

## Abstract (η^6^‐Arene)ruthenium(II) complexes of the type [{[η^6^‐C~6~H~5~(CH~2~)~n~COOH]Ru(µ‐Cl)Cl}~2~] (2a, n = 1; 3, n = 3) with tethered carboxylate groups can be obtained by dehydrogenation of the appropriate cyclohexadiene with RuCl~3~·3H~2~O. Formation of a κO‐coordinated chelate in weakly