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Neutral Hexa- and Pentacoordinate Silicon(IV) Complexes with SiO6 and SiO4N Skeletons

✍ Scribed by Seiler, Oliver; Burschka, Christian; Fenske, Tassilo; Troegel, Dennis; Tacke, Reinhold

Book ID
111938469
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
220 KB
Volume
46
Category
Article
ISSN
0020-1669

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✍ Dr. Bastian Theis; JΓΆrg Weiß; Dr. W. Peter Lippert; Dr. RΓΌdiger Bertermann; Dr. πŸ“‚ Article πŸ“… 2012 πŸ› John Wiley and Sons 🌐 English βš– 698 KB

Two nutrients in one molecule: A zwitterionic Ξ»(5)Si,Ξ»(5)Si'-disilicate (1) was synthesized and characterized. It contains ligands that exclusively derive from natural products ((R,R)-tartaric acid, choline). Hydrolysis of 1 yields 2, which shows a remarkable kinetic stability in water. Upon dissolu