Neue Wege zum Aufbau von Te–N-Bindungen – Synthese, Struktur und Eigenschaften von Cl6Te2N2S

✍ Scribed by Haas, Alois ;Kasprowski, Jörg ;Pryka, Michael

• Publisher: Wiley (John Wiley & Sons)
• Year: 1992
• Tongue: English
• Weight: 322 KB
• Volume: 125
• Category: Article
• ISSN: 0009-2940
• DOI: 10.1002/cber.19921250704

✦ Synopsis

New Routes for the Formation of Te -N Bonds -Synthesis. Structure, and Properties of C16Te2N2S Besides ClzTkNSNSk (l), the reaction of Se(NS0)2 with TeC14 this reaction is the well-known salt [SezNzS]z+[AsF;]> Treatleads to the formation of [Se2N2S]$f[TeC1;]2 (2) and the bi-ment of TeC14 with Me$GiNSO in CHzClz provides 3 on a cyclic heterocycle C16TezNzS (3). The latter is also accessible preparative scale. Its structure has been determined by X-ray by treating Se(NS0)2 with TeClzAsF,. Another product of crystallography.