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Neue phosphido- und phosphinidenverbrückte Quecksilbercluster: Die Kristallstrukturen der Mehrkernkomplexe [Hg3{Fe(CO)4}2X2] (X = Cl, Br) (1, 2), [Hg10{Fe(CO)4}4(PtBu)4Cl4] (3), [Hg14{Fe(CO)4}5(PtBu)8Cl2] (4), [SiMe3OPiPr3][Hg12{Fe(CO)4}7(PtBu)4(PtBuSiMe3)Br2] (5), [Hg5{Fe(CO)4}3(PtBu2)2Br2] (6), [Hg8{Fe(CO)4}4(P2Ph2)2(PnPr3)Cl4] (7), [Hg8{Fe(CO)4}4(P2Ph2)2(PPh2Et)Cl4] (8) und [Hg10{Fe(CO)4}6(P2Ph2)2(PnPr3)Br4] (9)

✍ Scribed by Jan Eisenmann; Dieter Fenske; Frank Hezel


Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
265 KB
Volume
624
Category
Article
ISSN
0372-7874

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Addition des O'Donnell Reagenzes [Ph2C=N
✍ Theodor Ederer; Karlheinz Sünkel; Wolfgang Beck 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 126 KB

The addition of [Ph 2 C=NCHCO 2 Me] ± to [(C 6 H 7 )Fe(CO) 3 ] + , [(C 7 H 9 )Fe(CO) 3 ] + , [(C 7 H 7 )M(CO) 3 ] + (M = Cr, Mo) and [(C 2 H 4 )Re(CO) 5 ] + gives derivatives of aamino acids with organometallic side chains. The structure of [(g 4 -C 6 H 7 )CH(N=CPh 2 )CO 2 Me]Fe(CO) 3 was determined