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Neue Phellandren-Derivate aus dem Wurzelöl von Angelica archangelicaL

✍ Scribed by Sina Escher; Urs Keller; Bruno Willhalm

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
776 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis

New Phellandrene Derivatives from the Root Oil of Angelica archangelica L.

2‐Nitro‐1,5‐p‐menthadiene (5), trans‐ and cis‐6‐nitro‐1(7), 2‐p‐menthadiene (6 and 7), trans‐1(7), 5‐p‐menthadien‐2‐yl acetate (9) and a formal phellandrene derivative, 7‐isopropyl‐5‐methyl‐5‐bicyclo [2.2.2]octen‐2‐one (16), have been identified in the root oil of Angelica archangelica L. Starting from (−)‐(R)‐α‐phellandrene (1) (R)‐5, (4__R__, 6__S__)‐6/(4__R__, 6__R__)‐7, (2__S__, 4__R__)‐9 and (1__R__, 4__R__, 7__R__)‐16 as well as (2__S__, 4__R__)‐11, (2__R__, 4__R__)‐12 and (2__R__, 4__R__)‐10 have been prepared.

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