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Network formation in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion: Effect of macroinitiator hydrophilicity

✍ Scribed by Md. Nur Alam; Per B. Zetterlund; Masayoshi Okubo

Book ID
108249892
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
351 KB
Volume
50
Category
Article
ISSN
0032-3861

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Nitroxide-mediated radical copolymerization of styrene (99 mol%)/divinylbenzene (1 mol%) employing the nitroxide 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) in aqueous miniemulsion using sodium dodecylbenzenesulfonate as surfactant has been carried out at 125 C. At a given styrene conversion, the d