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Neighboring Group Participation in a Regio- and Stereoselective Chlorination of a Bicyclo[2.2.2]octanone

✍ Scribed by Almqvist, Fredrik; Frejd, Torbjörn


Book ID
115491901
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
140 KB
Volume
61
Category
Article
ISSN
0022-3263

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A regio and stereoselective synthesis of
✍ T. Pathak; J. Chattopadhyaya 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 550 KB

Methyl B-D-arabinopyranoside (1) has been stereoselectively aeuterated, by the Treatment of deuteratgd Raney Ni in D 0, to give the 2,3.4-trideutereo-8-D-arabinopyranoside 2 in 33% yield. f t was then converted to 3.4-IsoproFylidene derivative Tb in 90% yield and subsequently derivatired to 2-D-phen