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Neighboring group participation by oxirane oxygen during oxymercuration of 1,5-diene monoxides

โœ Scribed by Closson, W. D.; Jernow, Jane L.; Gray, Donald


Book ID
125967719
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
746 KB
Volume
36
Category
Article
ISSN
0022-3263

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During alkaline methanolysis of the four stereoisomers l-4 of 3methoxy-17-~phenylcarbamoyloxy-l6-~tolylsulfonylox~ethylestra-l,3,5~10~-triene, a cyclization takes place, in the course of which the Wphenyltetrahydrooxazin-a-one derivatives 5-S are formed. The cis isomers 5, 8 and 8a-e are thermodynam