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Negative Thermal Expansion in Y2(WO4)3

โœ Scribed by David A. Woodcock; Philip Lightfoot; Clemens Ritter


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
213 KB
Volume
149
Category
Article
ISSN
0022-4596

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โœฆ Synopsis


FIG. 1. Structure of Y (WO ) showing YO octahedra (white), W(1)O tetrahedra (light gray), and W(2)O tetrahedra (dark gray).


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Sc 2 (WO 4 ) 3 has been found to show the highly unusual property of negative thermal expansion over a temperature range of 10 to 1073 K. Powder neutron diffraction data from 10 to 450 K shows an essentially linear decrease in cell volume as a function of temperature. The intrinsic linear coefficien

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The structure of tetragonal NbOPO 4 has been studied from room temperature to 500ยฐยฐC by X-ray powder diffraction and to 327ยฐยฐC by neutron powder diffraction. Rietveld refinements were conducted on neutron data collected at 25, 100, 175, 200, 225, 275, and 327ยฐยฐC. A phase transition was found at abou