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Negative-ion mass spectra of some pyridines, pyrazines and their N-oxides

✍ Scribed by William W. Paudler; Sharon A. Humphrey

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
267 KB
Volume
4
Category
Article
ISSN
1076-5174

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✦ Synopsis

The negative-ion mass spectra of some pyridines, pyrazines and their N-oxides are reported. All of the compounds examined fragment by generation of CN-ions. The alkylated derivatives readily form [M -11 anions. Most of the N-oxides yield 0and OH-ions. Polar substituents control the fragmentation processes involving the heterocyclic ring to which they are bonded.

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