Necking mechanism and its elimination in uniaxially drawn films of poly(ethylene naphthalate) (PEN)/polyetherimide (PEI) blends
✍ Scribed by M. Cakmak; J. C. Kim
- Book ID
- 101255648
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 484 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
✦ Synopsis
The influence of blend composition on the deformation behavior of cast amorphous PEN/PEI blends were investigated above their respected glass transition temperatures. PEN inherently shows a sharp necking phenomenon when stretched at temperatures as high as 20ЊC above its glass transition temperature. This was attributed to highly localized rapid alignment of naphthalene planes parallel to the surface of the films. The addition of PEI was observed to reduce this necking behavior. The neck formation completely disappears when the PEI fraction exceeds 10% in the blend. X-ray studies indicate that the increase of PEI hinders the rapid alignment of naphthalene planes parallel to the surface of the films. The presence of PEI chains in the blend was found to increase the overall friction between the polymer chains in the system and this was found to prevent the formation of highly localized necks.