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Near threshold photodissociation of expansion cooled NCNO: Nascent CN(X2Σ+) without internal excitation

✍ Scribed by I. Nadler; H. Reisler; M. Noble; C. Wittig


Book ID
103027992
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
750 KB
Volume
108
Category
Article
ISSN
0009-2614

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✦ Synopsis


The dissociation of cspJn,ion cooled NCNO follo\ving 'i t tion. 2nd ~hc CN(r; 'z+ .L" -7 ' A' excitation transpires via vibrational predissocia-) fragmcn~s arc exrro~re~~~ cold ncdr reaction threshold. Only u" = 0 is produced. and >902 of rhc CN is in 11"' = 0 corresponding IO tlr'intcrnal) <0.1 cm-1 X rcviscd v~luc for rhe NCNO dissociation cnrrgy (Do = 17085 + 10 cm-' ) is rcportcd.