Near-Infrared Fourier Transform Raman Spectroscopy of B12 Models. 4. Steric and Electronic Factors Affecting the Co-C Bond in Organocobalt Complexes

A Molecular Mechanics Force Field for Al

A Molecular Mechanics Force Field for Alkylcobaloximes, a Model of Vitamin B12 Coenzyme – Implications of Steric and Electronic Factors in the Co–C Bond Cleavage

✍ Silvano Geremia; Mario Calligaris; Lucio Randaccio 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 441 KB 👁 2 views

Molecular mechanics force field constants have been derived correlated with their calculated cone angles. The force field has been used to analyse some conformational features of for alkylcobaloximes, (alkyl)Co(DH) 2 L (DH = monoanion of dimethylglyoxime and L = planar N-donor ligand), these compoun