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Near infrared cw-CRDS coupled to laser photolysis: Spectroscopy and kinetics of the HO2radical

✍ Scribed by J. Thiébaud; C. Fittschen


Book ID
106027223
Publisher
Springer
Year
2006
Tongue
English
Weight
446 KB
Volume
85
Category
Article
ISSN
0721-7269

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✍ Sebastien Dusanter; Lahcen Elmaimouni; Christa Fittschen; Bernard Lemoine; Pasca 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB

## Abstract The rate constants __k__~d~ for the unimolecular decomposition of two acyl (RĊO) radi‐ cals: 2,2‐dimethylpropionyl (CH~3~)~3~CĊO and 2‐methylpropionyl (CH~3~)~2~CHĊO (pivaloyl and isobutyryl, respectively in what follows) have been directly measured via the time‐resolved kinetics of CO