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Nature of Ti Interstitials in Reduced Bulk Anatase and Rutile TiO 2

✍ Scribed by Finazzi, Emanuele; Di Valentin, Cristiana; Pacchioni, Gianfranco

Book ID
125444236
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
873 KB
Volume
113
Category
Article
ISSN
1932-7447

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πŸ“œ SIMILAR VOLUMES

Electrostatic potential calculations on
Electrostatic potential calculations on crystalline TiO2: The surface reducibility of rutile and anatase
✍ J. Ivoning; R.A. van Santen* πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 569 KB

From calculations of the electrostatic potential at the most densely packed rutile (110) and anatase (001) crystal faces. greater reducibility of the coordinatively unsaturated Ti4' \_ Ions at the rutile surface than at the anatase surface is predicted. Consequently, the intrinsic hewis acidity of c