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Nature of the transition state in gas phase SN2 identity reactions: correlation between nucleophilicity and proton affinity

โœ Scribed by Uggerud, Einar


Book ID
121722089
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
133 KB
Volume
7
Category
Article
ISSN
1472-779X

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The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')