Nature of the solvent effect in the infrared spectra of carbonyl compounds
✍ Scribed by M. Horák; J. Jonáš; J. Plíva
- Publisher
- Elsevier Science
- Year
- 1959
- Tongue
- French
- Weight
- 193 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Y I-CII-9~ paPer aevoteo to tm lnveatlga~on of the errect Or aoxvents on the characteristic frequencies of various bonda haa appeared in recent literature.1*
In aome of these papers the authors l-3 related the observed frequency shifts due to the solvent to ease speciffc property of the solvent swh aa the dielectric conetaut or the refractive Index 011 the saeumption of the validity of the Kirkwood-Bauer4agat theory. 687 A new approach to the etudy of the solvent effect can be men in ths recent CWF munlcations by Archibald and Pullin and by Bellamy, Eallaa~, and Williama in which the effect of the solvent was ahom to depend both on the pry pertles of the sclvent and on the character of the bold comerned.
📜 SIMILAR VOLUMES
The infrared and Raman spectra of carbonyl diisocyanate have been recorded. Vibrational assignments have been made on the basis that two planar conformations are present both in the liquid and vapour phases: cis-cis and cb-trans. Simple normal coordinate calculations have been used to confirm the as