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Nature of the Metal-Carbon Triple Bond. A Reevaluation of the M.tplbond.C Stretching Frequency and Force Constant

✍ Scribed by Manna, Joseph; Kuk, Raymond J.; Dallinger, Richard F.; Hopkins, Michael D.


Book ID
126982251
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
257 KB
Volume
116
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES


Stretching Frequency and Force Constant
✍ Prof. Dr. Ernst Otto Fischer; Dr. Nguyen Quy Dao; Dipl.-Chem. Wolfgang Rainer Wa 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB

bulky groups. In the erythro series, on the other hand, chelation requires an increase in the proportion of (E,) or (Ec), and 5 2 3 progressively decreases to a limiting value which agrees closely with the calculated figure. Although both of these rotamers have four adjacent bulky groups, chelation