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Nature of the Intermediates in Gold(I)-Catalyzed Cyclizations of 1,5-Enynes

✍ Scribed by Verónica López-Carrillo; Núria Huguet; Ángeles Mosquera; Prof. Antonio M. Echavarren

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 594 KB
Volume: 17
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201101749

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The authors have recently found that the configuration of diene 64 (Ar = p-MeOC 6 H 4 ) in Scheme 6 was incorrectly assigned. The major isomer has a cis configuration, whereas the configuration of related compounds 62 and 66 (Ar = Ph and p-O 2 NC 6 H 4 ) is trans as reported. The correct configurati