Nature of boron in α-iron
✍ Scribed by Y Hayashi; T Sugeno
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 452 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0001-6160
No coin nor oath required. For personal study only.
✦ Synopsis
Internal friction measurements were carried out on iron-boron and iron-nickel-boron
alloy specimens, in order to define the nature of the boron solid solution in a-iron. An internal friction peak corresponding to a small amount of boron in a-iron was observed.
Referring to the lattice parameter measurements, and the diffusion experiment, it can be concluded that boron atoms occupy both substitutional and interstitial positions. The concept of dissociative diffusion explains well the diffusion mechanism of boron i;;;ir;r.
The relaxation time of the jump of an interstit,ial boron atom is shown to be 1O-13 exp (13000/ 6 .
SATURE
DG BORE DANS LE FER-ALPHA Des mesures de frottement interne ont 6tB me&es iL bien sur des Bchantillons d'alliage fer-bore et d'alliage fer-nickel-bore dans le but de dbfinir la nature de la solution solide de bore dans le fer-a. En se &f&rant aus mesures des param&tres du rQseau et) aux expbriences de diffusion, les auteurx concluent que les atomes de bore occupent B la fois des posit,ions interstitielles et de subst.itution. Le concept de la diffusion dissoci& explique bien le mecanisme de diffusion du bore dans le fer-a. Les auteurs montrent que le temps de relaxation correspondant au saut d'un atome interstitiel de bore est de lo-l3 exp (130001 RT) sec. OBER DIE SATUR DES BORS IS a-EISES Zur Bestimmung der Satur der festen LGsung van Bor in a-Eisen wurden RIessungen der inneren Reibung an Eisen-Bor-und Eisen-Nickel-Bor-Legierungen durchgefiihrt. Ein Maximum der inneren Reibung, das einer kleinen Menge van Bor in a-Eisen entsprach, wurde beobachtet. Aus Messungen der Gitterperameter und aus Diffusionsexperimenten kann geschlossen werden, dal3 die Boratome sowohl Gitter-als such Zwischengitterpliitze einnehmen. Die Vorstellung der dissoziativen Diffusion erkliirt gut. den Diffusionsmechanismus van Bor in a-Eisen. Zwischengitteratomo ist lo-l3 exp (13000/RT) sec.
Die Relaxationszeit des Sprungs eines Bor-
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