𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Natural bond orbital analysis of the intrinsic reaction barriers in nucleophilic displacements

✍ Scribed by Lee, Ikchoon

Book ID
121501600
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
341 KB
Volume
22
Category
Article
ISSN
0144-235X

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Semi-empirical natural orbital analysis
Semi-empirical natural orbital analysis of the bonding and rotational energy barrier in cyclopropylmethyl cation
✍ E. Yurtsever; J. Moreshead; D. Shillady πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 365 KB

The Boys-Reeves Cl algorithm has been applied in a CNDO/?. framework to study the bonding in the cyclopropylmethyi cation. 1n:erpretive use is made of the fact that the CI algorithm is identical to a v;llence bond calculation except for the restriction to orthonormal one-electron orbit&. A pseudo-n

Displacement of Activated Amino Groups.
Displacement of Activated Amino Groups. C,N- vs. N,S-Bond Cleavage in the Reaction of N-Alkyl-disulfonamides with Nucleophiles
✍ Paul MΓΌller; Minh Phuong Nguyen Thi πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 German βš– 531 KB

## Abstract Sodiumthiophenoxide and sodiumphenylselenide react with __N__‐benzyl‐ and __N__‐hexyl‐di‐__p__‐toluenesulfonamides (**1** and **2**) __via__ displacement at the C‐atom to afford the corresponding organosulfides and selenides in yields of 68–96%. In contrast, sodium cyanide converts disu