Natural abundant solid state NMR studies in designed tripeptides for differentiation of multiple conformers
✍ Scribed by S. Jayanthi; Bhaswati Chatterjee; S. Raghothama
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2009
- Tongue
- English
- Weight
- 371 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0006-3525
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## Abstract Natural abundance solid‐state ^25^Mg NMR measurements were made of the disodium salt of magnesium ethylenediaminetetraacetate tetrahydrate (Na~2~MgEDTA·4H~2~O). Both magic angle spinning (MAS) and static experiments were employed to determine the quadrupole coupling constant (__C__~q~)
## Abstract Recently, a sequence for heteronuclear dipolar decoupling in solid‐state NMR, namely SW~__f__~‐TPPM, was introduced by us. Under magic‐angle spinning (MAS), the decoupling efficiency of the sequence was unaffected over a range of values for various experimental parameters such as the pu