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[Na(THF)2(μ2- η5- Cp)(η5, η5, η1-Cp3Yb)(THF)]n: The synthesis and X-ray structure of an anionic organolanthanide polymer formed via self-assembly

✍ Scribed by Huang Dan, Sun Hongmei, Liu Taiqi, Xu Fan, Shen Qi


Book ID
120803097
Publisher
Springer
Year
2005
Tongue
English
Weight
965 KB
Volume
50
Category
Article
ISSN
1001-6538

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Organometallic Compounds of the Lanthani
✍ Herbert Schumann; Markus R. Keitsch; Jörg Demtschuk; Stefan Mühle 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 171 KB 👁 2 views

The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4