𝔖 Bobbio Scriptorium
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Naphtho[1,8-ab:4,5-a′b′]diazulene, the first nonalternant isomer of dibenzopyrene

✍ Scribed by Yoshimasa Fukazawa; Muneo Aoyagi; Shô Itô


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
199 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis


The title compound was synthesized by the tronsannular reaction of E2.21(1,3)azulenophane and subsequent dehydrogenotion. It exhibits characteristic electronic absorption bonds extended to neor IR region (-1400 nm) and its PMR spectrum indicates the presence of large ring current. MO calculations suggest no bond alternation in the entire II system.


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