𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Nanostructured Thermosetting Systems from Epoxidized Styrene Butadiene Block Copolymers

✍ Scribed by Elena Serrano; M. Dolores Martin; Agnieszka Tercjak; Jose A. Pomposo; David Mecerreyes; Iñaki Mondragon

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
240 KB
Volume
26
Category
Article
ISSN
1022-1336

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Summary: Nanostructured thermosetting materials were prepared by modification of an epoxy resin with 30 wt.‐% epoxidized polystyrene‐block‐polybutadiene copolymer (PS‐b‐PepB). The copolymer self‐assembles into a well‐defined hexagonal nanoordered structure, of around 30‐nm diameter, thus establishing its use as structure‐directing agent to generate nanostructured thermosetting materials. The study confirms pathways towards tailoring interactions between thermosetting matrices and immiscible block copolymers by using the concept of functionalization to build nanostructured polymer matrices.

Structure of diglycidyl ether of bisphenol‐A/4,4′‐methylenebis(3‐chloro 2,6‐diethylaniline) cured blend containing 30 wt.‐% PS‐b‐PepB61 block copolymer.

magnified imageStructure of diglycidyl ether of bisphenol‐A/4,4′‐methylenebis(3‐chloro 2,6‐diethylaniline) cured blend containing 30 wt.‐% PS‐b‐PepB61 block copolymer.

📜 SIMILAR VOLUMES

Synthesis and Characterization of Epoxid
Synthesis and Characterization of Epoxidized Styrene-Butadiene Block Copolymers as Templates for Nanostructured Thermosets
✍ Elena Serrano; Maider Larrañaga; Pedro M. Remiro; Iñaki Mondragon; Pedro M. Carr 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 431 KB

## Abstract **Summary:** A wide range of epoxidized styrene‐block‐butadiene block copolymers were synthesized using hydrogen peroxide in the presence of an in situ prepared methyltrioctylammoniumtetrakis(diperoxotungstate)phosphate as the catalyst system in a water/dichloroethane biphasic system. ^

Curing Behavior and Final Properties of
Curing Behavior and Final Properties of Nanostructured Thermosetting Systems Modified with Epoxidized Styrene-Butadiene Linear Diblock Copolymers
✍ Elena Serrano; Agnieszka Tercjak; Connie Ocando; Maider Larrañaga; M. Dolores Pa 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 554 KB

## Abstract Nanostructured thermosetting materials based on thermosetting matrices were prepared by modification of an epoxy system with linear PS‐__block__‐PB copolymers. The nanostructured thermosets were obtained through PS block segregation. Depending on the block‐copolymer content in the therm