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Nanoscale Ionic Materials

✍ Scribed by Robert Rodriguez; Rafael Herrera; Lynden A. Archer; Emmanuel P. Giannelis


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
295 KB
Volume
20
Category
Article
ISSN
0935-9648

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✦ Synopsis


Abstract

Polymer nanocomposites (nanoparticles dispersed in a polymer matrix) have been the subject of intense research for almost two decades in both academic and industrial settings. This interest has been fueled by the ability of nanocomposites to not only improve the performance of polymers, but also by their ability to introduce new properties. Yet, there are still challenges that polymer nanocomposites must overcome to reach their full potential. In this Research News article we discuss a new class of hybrids termed nanoparticle ionic materials (NIMS). NIMS are organic–inorganic hybrid materials comprising a nanoparticle core functionalized with a covalently tethered ionic corona. They are facilely engineered to display flow properties that span the range from glassy solids to free flowing liquids. These new systems have unique properties that can overcome some of the challenges facing nanocomosite materials.


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Fig. 6. Graphical illustration of the stages involved in the evolution of a liquid crystal film on graphite: A) surfactant monolayer; B) hemicylindrical micellar monolayer; C) vectorial nucleation of worm-shaped mesostructures: D) liquid crystal film; E) liquid crystal film with non-rigid outer zone