The Gibbs adsorption isotherm and Wagner's definition of excess solute at surfaces and grain boundaries are both extended to include other crystalline defects, like dislocations and vacancies. By using a thermodynamic state function which is suitable for a partially open system, open with respect to
โฆ LIBER โฆ
Nano-scale grain growth inhibited by reducing grain boundary energy through solute segregation
โ Scribed by Feng Liu; Reiner Kirchheim
- Book ID
- 108165693
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 255 KB
- Volume
- 264
- Category
- Article
- ISSN
- 0022-0248
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The extended version of the Gibbs adsorption isotherm including dislocations and vacancies is used to analyse existing experimental data. Thus phenomena and models like solid solution softening, hydrogen-enhanced local plasticity, brittleness of hydrides and superabundant vacancies could be interpre