Nano copper ferrite: A reusable catalyst for the synthesis ofβ,γ-unsaturated ketones
✍ Scribed by Y L N MURTHY, B S DIWAKAR, B GOVINDH, K NAGALAKSHMI, I V KASI VISWANATH, RAJENDRA SINGH
- Book ID
- 113094203
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 356 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0253-4134
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A/~tract:. A new, one pot synthesis of bicyclic ethers starting from ct, l~-unsaturated ketones containing an additional isolated olefinic bond is proposed. It relies on highly chemoselective hydrogenation of the enone group to the corresponding alcohol in the presence of supported copper catalysts,
A general procedure for the Michael addition of pyrroles with ␣,-unsaturated ketones using catalytic amount of Amberlyst-15 at room temperature has been developed. This method is fast, efficient, high yielding and eco-friendly to afford the corresponding Michael adducts generally in good to excelle