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Name Reactions || Jacobsen–Katsuki epoxidation

✍ Scribed by Li, Jie Jack

Book ID
120433204
Publisher
Springer Berlin Heidelberg
Year
2009
Weight
131 KB
Category
Article
ISBN
3642010539

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Epoxidation reactions have been established as an important method for the formation of carbon-oxygen bonds. In 1980 Sharpless and Katsuki developed an enantioselective variant for allylic alcohols which is still one of the most elegant methods in asymmetric synthesis. ['] Over the last few years un

Selectivity Enhancement for the Jacobsen
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## Abstract magnified image In 1,1,1,2,3,4,4,5,5,5‐Decafluoropentane using 2‐phenylpyridine __N‐__oxide as donor ligand, the enantioselectivity of the __Jacobsen–Katsuki__ epoxidation is improved up to 10% ee as compared to established protocols.

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