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NADH models: II. Mechanism of reduction of electrophilic olefins with 3,5-diethoxycarbonyl-2,6-dimethyl-1,4-dihydropyridine (1)

✍ Scribed by U.K. Pandit; J.B. Steevens; F.R.Mas Cabré


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
465 KB
Volume
2
Category
Article
ISSN
0045-2068

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✍ Bruno Hardegger; Shimon Shatzmiller 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 236 KB 👁 1 views

## Abstract Preparation of 2,3‐Dimethyl‐5,6‐dihydro‐4__H__‐1,2‐oxaziniumiodide was achieved by N‐alkylation of 3‐methyl‐5,6‐dihydro‐4__H__‐1,2‐oxazine. Reactions with C‐nucleophiles led to the corresponding N‐methyl‐perhydro‐1,2‐oxazine derivatives. Reaction with sodium hydride in triglyme led to 3