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Nachbargruppeneffekte bei der massenspektrometrischen Fragmentierung: N-Acetyl-ω-Phenylalkylamine. 20. Mitteilung über das massenspektrometrische verhalten von stickstoffverbindung

✍ Scribed by René Wild; Manfred Hesse

Publisher: John Wiley and Sons
Year: 1974
Tongue: German
Weight: 805 KB
Volume: 57
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19740570219

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✦ Synopsis

Abstract

The mass spectral behaviour of the difunctional alkane N‐acetyl‐4‐phenyl‐butylamine (3) was investigated. The main fragmentation of compound 3 is caused by the interaction on the two functional groups, which could be shown by comparison of the corresponding monofunctional compounds n‐butylbenzene (4) and N‐acetyl‐n‐butylamine (5). On the bases of high resolution data, the analyses of metastable transitions and the comparison of the spectra of some homologs and deuterated analogs of 3 the structures and their genesis of the main fragment ions were deducted.

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