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Na2ZnGe

✍ Scribed by Cheviré, François ;DiSalvo, Francis J.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
116 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The structure of disodium zinc germanide, Na 2 ZnGe, has been determined from single-crystal data and is reported for the first time. The compound crystallizes in the Na 2 CuAs structure type. The structure is built of Na + ions (8g position) and infinite zigzag chains of (ZnGe) 2À parallel to the c axis (Zn and Ge atoms are in 4b and 4c positions, respectively).


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Refractive indices and their dispersion in the wavelength range from 365 nm to 2325 nm and transmission ranges of the tetragonal melilite-type germanates Sr 2 MgGe 2 O 7 , Sr 2 ZnGe 2 O 7 and Ba 2 ZnGe 2 O 7 were determined. The uniaxial positive crystals Sr 2 MgGe 2 O 7 and Ba 2 ZnGe 2 O 7 both off