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Na2.54Cs1.14Mo9S11, a quaternary reduced molybdenum sulfide containing Mo9 clusters

โœ Scribed by Salloum, D. ;Gougeon, P. ;Potel, M.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
274 KB
Volume
62
Category
Article
ISSN
1600-5368

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K2Mo15S19: a novel ternary reduced molybdenum sulfide containing Mo6 and Mo9 clusters
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K 2 Mo 15 S 19 (potassium molybdenum sulยฎde) crystallizes in the trigonal space group R3c and belongs to the In 2 Mo 15 Se 19 structure type. Its crystal structure consists of an equal mixture of Mo 6 S 8 and Mo 9 S 11 cluster units interconnected through MoรS bonds. The K + cations occupy large voi

Rb2n(Mo9S11)(Mo6nS6n+2) (n=1 to 4): A No
Rb2n(Mo9S11)(Mo6nS6n+2) (n=1 to 4): A Novel Family of Superconducting Molybdenum Cluster Compounds
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Reinvestigation of the Rb+Mo+S system has led to the discovery of a novel family of reduced molybdenum sul5des with the general formula Rb 2n (Mo 9 S 11 )(Mo 6n S 6nุ‰2 ) (n โ€ซุโ€ฌ 1 to 4) in addition to the previously known compound Rb 2 Mo 6 S 6 . The new rubidium-reduced molybdenum sul5des have been