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N2-Eliminierung eines [3 + 2]-Cycloadduktes aus Diazoalkan und Amino(methylen)phosphan zu einem λ3-Phosphiran

✍ Scribed by Prof. Dr. Edgar Niecke; Priv.-Doz. Dr. Wolfgang W. Schoeller; Dirk-Andreas Wildbredt

Book ID
101521105
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
209 KB
Volume
93
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

N2-Elimination from a [3 + 2]-Cycloadduc
N2-Elimination from a [3 + 2]-Cycloadduct of Diazoalkane and Amino(methylene)phosphane to give a λ3-Phosphirane
✍ Prof. Dr. Edgar Niecke; Priv.-Doz. Dr. Wolfgang W. Schoeller; Dipl.-Chem. Dirk-A 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 228 KB

These distances indicate considerable mesomeric interaction of the free electron pair on C52 with the )C=O groups, with the free electron pair on the imide nitrogen, and with the phosphorus atoms. The cyclopentadiene ring in (5) is pentahapto bonded to molybdenum. The bond lengths in the M O ( C O )