In the title compound, C 24 H 38 N 2 O 6 S 2 , which was synthesized from (+)-10-camphorsulfonic acid chloride and piperazine, the central piperazine ring adopts a chair conformation. The two camphorlsulfonyl groups are bound to the piperazine N atoms in equatorial positions. The molecule has approx
✦ LIBER ✦
N2-(2-Nitrophenylsulfonyl)-N5-n-propylglutamine
✍ Scribed by Xiao, Yong-Jun ;Wang, Jian-Guo ;Li, Zheng-Ming ;Song, Hai-Bin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 184 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, C 14 H 19 N 3 O 7 S, is a potent new herbicide. X-ray analysis reveals that the nitro group is twisted away from the benzene ring and the glutamine residue adopts a folded conformation. The crystal packing is stabilized by intermolecular N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds.
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The crystal packing in the title compound, C 15 H 16 N 2 O 2 S, consists of an NÐHÁ Á Á% pyrrole , a CÐHÁ Á Á% pyrrole , a CÐ HÁ Á Á% phenyl and two CÐHÁ Á ÁO interactions.