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n → π* Interaction and n)(π Pauli Repulsion Are Antagonistic for Protein Stability

✍ Scribed by Jakobsche, Charles E.; Choudhary, Amit; Miller, Scott J.; Raines, Ronald T.

Book ID
111985906
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
234 KB
Volume
132
Category
Article
ISSN
0002-7863

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In many common protein secondary structures, such as alpha-, 3(10), and polyproline II helices, an n --> pi\* interaction places the adjacent backbone amide carbonyl groups in close proximity to each other. This interaction, which is reminiscent of the Burgi-Dunitz trajectory, involves delocalizatio

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